Taking advantage of a recent FORS2/VLT spectroscopic sample of Extreme Horizontal Branch (EHB) stars in ω Cen, we isolate 38 spectra well suited for detailed atmospheric studies and determine their fundamental parameters (T eff , log g, and log N (He)/N (H)) using NLTE, metal line-blanketed models. We find that our targets can be divided into three groups: 6 stars are hot (T eff > ∼ 45,000 K) H-rich subdwarf O stars, 7 stars are typical H-rich sdB stars (T eff < ∼ 35,000 K), and the remaining 25 targets at intermediate effective temperatures are He-rich (log N (He)/N (H) > ∼ −1.0) subdwarfs. Surprisingly and quite interestingly, these He-rich hot subdwarfs in ω Cen cluster in a narrow temperature range (∼35,000 K to ∼40,000 K). We additionally measure the atmospheric carbon abundance and find a most interesting positive correlation between the carbon and helium atmospheric abundances. This correlation certainly bears the signature of diffusion processes -most likely gravitational settling impeded by stellar winds or internal turbulence -but also constrains possible formation scenarios proposed for EHB stars in ω Cen. For the He-rich objects in particular, the clear link between helium and carbon enhancement points towards a late hot flasher evolutionary history.