Well-known
kinetic hydrate inhibitors (KHIs) such as poly(N-vinylcaprolactam)
(PVCap), poly(N-vinylpyrrolidone)
(PVP), and 1:1 N-vinylcaprolactam:N-vinylpyrrolidone (VCap:VP) copolymer have been subjected to a range
of treatments to determine their reliability and whether the treatment
conditions could affect the KHI performance, both positively or negatively.
This included thermal aging (at varying temperatures, at varying pH,
and in monoethylene glycol (MEG) solvent), treatment with microwaves
or ultrasound, ball-milling, and oxidizing agents (household bleach
or hydrogen peroxide, also with heat). In addition, samples of commercial
polymer solutions kept for up to 15 years were also tested for KHI
performance to determine their long-term reliability. Testing was
carried out using a synthetic natural gas mixture in steel rocking
cells using slow constant cooling starting at ca. 76 bar. All samples
of PVCap and 1:1 VP:VCap showed good KHI performance to the first
sign of hydrate formation, but older samples showed a better ability
to inhibit crystal growth. KHI polymer testing after treatment with
microwaves or ultrasound, or thermal aging (at varying temperatures,
varying field pH, and in MEG solvent up to 160 °C) showed little
loss of performance. Oxidizing agents, particularly sodium hypochlorite
solution, worsened the KHI performance.