“…They are very promising because they attracted much attention due to their physical properties in different field: optical properties [8], Semiconducting [9], Ferroelectricity [10], (anti)-ferromagnetism, magnetoresistance [11,12], and many others technological applications [13][14][15][16][17]. Fluoro-perovskites (Fluorides) ABF 3 doped with Mn 2+ show unique photo and thermo stimulated luminescence [18,19], Dielectric [18,20], optical [18,21], Mechano-lumescente, thermos power [18,22], piezoelectric, laser source, catalytic and magnetoresistance properties, solid-state fuel cell, oxygen membranes [23,24]. Crystals with ABF 3 have been a subject of immense interest also due to high temperature proton conductors with the possibility of applications in fuel cells or hydrogen sensors, crystal field [25,26].…”