“…Over the past few decades, several techniques for enhancing TE materials have emerged. Some techniques that aim to enhance the power factor are resonant state doping [71], band convergence [75], quantum confinement [76], minority carrier blocking [77], while others focus on reducing the total thermal conductivity using nanostructuring [69][70][71], hierarchical architecture [72][73][74], Researchers have employed the above techniques to improve the TE properties of all kinds of materials, including MCs [75][76][77], skutterudites [78][79][80][81], half Heusler [82][83][84], silicide [85,86] and oxides [87][88][89][90]. Focusing on enhancing TE performance in MCs using isovalent substitution, it will be shown below how it has revolutionised the thermoelectricity sector.…”