2024
DOI: 10.1002/mrc.5470
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A theoretical study of the electron paramagnetic resonance spectra and local environment in copper(II) complexes with different imidazole and chlorido ligands

Jun‐Shan Hu,
Xin‐Xin Wang,
Si‐Qi Li
et al.

Abstract: Copper(II) chloride anionic coordination complexes with different imidazole‐derived ligands due to the potential cytotoxic activity play the important role in protein. By investigating the experimental electron paramagnetic resonance (EPR) and ultraviolet–visible (UV–vis) spectra of [CuCl(C6H10N2)4]Cl, [CuCl(C6H10N2)4]Cl, [CuCl2(C4H6N2)4], and [Cu2Cl2(C5H8N2)6]Cl2·2H2O, the local structure of the corresponding Cu2+ centers and the role of different ligands are obtained. Based on the well‐agreed EPR parameters … Show more

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