Silver (Ag) nanoalloys play significant
roles in several industrial
applications. While still many sustainable frameworks can be explored
for the synthesis and functional incorporations, the control of phase
and structure at the nanoscale still is a major challenge for their
practical implementation. In this study, liquid-phase gallium (Ga(L)) nano-/microspheres were utilized for this purpose, investigating
their function as reaction media and metallic alloying elements for
the development of one-dimensional (1D) Ag–Ga nanoalloys from
a silver fluoride precursor. Ultrasonic input at near room temperature
was selected for the green synthesis method. The mechanisms for the
nucleation, anisotropic growth, and morphological development under
ultrasonic oscillations were comprehensively analyzed. The experimental
outcomes revealed that the development of 1D Ag–Ga nanoalloys
was in correlation with the ultrasonic exposure time, influencing
the inter-/intraparticle interactions, modulating the Ga(L) nano-/microsphere dimensional and structural properties, and establishing
Ag–Ga bimetallic core–shell microsystems accordingly.
The subsequent self-assembly mechanisms were observed to have been
primarily driven by Ga(L) surface tension and intermolecular
forces promoting spontaneous Ag–Ga liquid–solid interfacial
wetting and intermetallic diffusion. The nucleation and crystallization
of the 1D nanoalloys developed following two possible pathways for
the differentiation of morphologies in the form of either nanoneedles
or nanorods identified as the Ag2Ga crystal phase. We observed
that the key advantage of Ga(L) nano-/microspheres as the
reaction media is the direct control of the phase and morphological
development of the 1D Ag–Ga batch structures, demonstrating
a straightforward route for the green synthesis of engineered nanoalloys
for catalytic applications.