The high quality standards of copper produced commercially today depend upon two process factors: (i) the effectiveness of the primary extraction step in safely eliminating damaging minor impurity elements; and (ii) the sustained refining capabilities of electrolytic cathode production. The principal source of new copper remains the sulphidic ores, and the evolution of primary extraction technology for sulphides from the mid-19th century to the present is briefly reviewed in relation to impurity treatment. Earlier industrial uses of copper in, for example, the sheathing of wooden ships' hulls, were tolerant of the relatively high impurity levels in fire refined copper, although the significance of impurities on service life was recognised. Modern electrolytic refining, which began in Wales in 1869, grew out of the Victorian fascination with decorative electrodeposition. By that time, studies of the links between copper composition and electrical conductivity in relation to the development of the submarine telegraph cable were beginning to show the crucial importance of copper purity for electrical applications. The rapid growth of these applications around the turn of the century produced a corresponding growth in demand for high purity copper, establishing electrorefining as the basis for modern, and increasingly exacting, quality standards. This growth has taken place against a background of profound changes in the geographical location, complexity and mineral processing of mineable copper deposits which continue to challenge the achievement of those standards. P. J. Mackey is at Noranda-Falconbridge, Falconbridge Technology Centre, Montreal Office, 2250 boul. Alfred Nobel, St Laurent QC, Canada H4S 2C9 and A. E. Wraith is in the