A three-component mixed-matrix membrane with enhanced CO2 separation properties based on zeolites and ionic liquid materials

Hudiono, Yeny; Carlisle, Trevor K.; Bara, Jason E.; Zhang, Yanfeng; Gin, Douglas L.; Noble, Richard D.

doi:10.1016/j.memsci.2009.12.018

Cited by 166 publications

(114 citation statements)

References 36 publications

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“…The main challenge in MMMs is the adhesion between dispersed and continuous phases. To improve adhesion, there are several strategies which have been studied, such as functionalization of the inorganic particles prior to introduction into the polymer matrix, or the incorporation of an ionic liquid in the membrane matrix (Hudiono et al 2010;Hao et al 2013). In a previous work, we proposed a similar approach but using a non-toxic ionic liquid, a biopolymer and a microporous zeo-type material prepared without organic surfactant (Casado-Coterillo et al 2014b).…”

Section: Introductionmentioning

confidence: 99%

Synergistic Effect of Combining Titanosilicate and 1-Ethyl-3-Methylimidazolium Acetate in Mixed Matrix Membranes for Efficient C02 Separation

López-Guerrero¹,

Casado-Coterillo²,

Irabien³

2015

EJSD

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The separation and capture of CO 2 from these sources is becoming important for greenhouse emission. The membrane-based separation process use to remove CO 2 takes advantages in energy efficient and environmentally friendly aspects and has been recognized as an important technology for CO 2 capture and gas separation. The novel mixed matrix membranes (MMMs) were fabricated by incorporating microporous titanosilicate ETS-10 and a highly CO 2 absorbent ionic liquid , [EMIM][Ac] into a Chitosan (CS) matrix to improve CO 2 separation performance, and were prepared, characterized and tested for CO 2 and N 2 . The solubility values show that the CO 2 solubility increases upon addition of ETS-10 particles. The N 2 solubility in the ETS-10/[EMIM][Ac]/CS was reduced, while CO 2 solubility remained constant. FT-IR spectra revealed a good interaction between the components in the MMMs. Subtle differences in the intensity and position of all individual bands, were observed in the region between 3600 and 2700 cm -1 and 1700 and 900 cm -1 . These indicated bonding of the components in the film, confirming the good interaction existing among the components, and that may account for the higher flexibility of the hybrid membrane materials imparted to both CS and ETS-10/CS MMMs, , due to the singular interaction between CS and [EMIM] [Ac].

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Section: Introductionmentioning

confidence: 99%

Synergistic Effect of Combining Titanosilicate and 1-Ethyl-3-Methylimidazolium Acetate in Mixed Matrix Membranes for Efficient C02 Separation

López-Guerrero¹,

Casado-Coterillo²,

Irabien³

2015

EJSD

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“…These studies imply that the incorporation of suitable LMWAs, which can be effective even at low concentrations to MMMs, can be appreciated as a favorable way to prepare highly selective gas separation membranes without deteriorating the permeabilities. Hudiono et al [18] recently prepared ternary component mixed matrix membranes of SAPO-34/polymerized ionic liquid/ionic liquid to measure single gas permeabilities of N 2 , CO 2 and CH 4 .…”

Section: Introductionmentioning

confidence: 99%

Preparation and performance assessment of binary and ternary PES-SAPO 34-HMA based gas separation membranes

Karatay

Kalıpçılar

Yılmaz

2010

Journal of Membrane Science

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“…The existence of RTIL component enhanced the interfacial adhesion between inorganic zeolite surface and organic polymer matrix. However, The CO 2 /CH 4 selectivity of threecomponent SAPO-34-RTIL-poly(RTIL) MMM was slightly lower, as compared to that of two-component SAPO-34-poly(RTIL) MMM [215] .…”

Section: Zeolite Fillers Fimentioning

confidence: 86%

CO2 Selective Separation Membranes

Yao

Wang

2013

Eco- And Renewable Energy Materials

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Over the past two decades, membrane technology has attracted tremendous attention at CO 2 separation from other gases, which has shown great potential to significantly improve energy efficiency and reduce cost associated with processes. The membrane structures and chemistry properties greatly affect their CO 2 separation performances, including selectivity and permeability. In recent years, there has been significant progress in the development of CO 2 -selective membranes. This chapter reviewed the recent activities relating to the fabrication and separation performances of polymeric, inorganic and mixed-matrix membranes for CO 2 separation purposes.

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A three-component mixed-matrix membrane with enhanced CO2 separation properties based on zeolites and ionic liquid materials

Cited by 166 publications

References 36 publications

Synergistic Effect of Combining Titanosilicate and 1-Ethyl-3-Methylimidazolium Acetate in Mixed Matrix Membranes for Efficient C02 Separation

Synergistic Effect of Combining Titanosilicate and 1-Ethyl-3-Methylimidazolium Acetate in Mixed Matrix Membranes for Efficient C02 Separation

Preparation and performance assessment of binary and ternary PES-SAPO 34-HMA based gas separation membranes

CO2 Selective Separation Membranes

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