A Three‐dimensional Dy^III‐based Metal‐organic Framework: Smart Drug Carrier and Anti‐lung Cancer Activity

Abstract

A 3D lanthanide metal-organic framework (MOF) with the formula [Dy 2 (L) 2 (H 2 O) 2 ] n (1) (H 3 L = biphenyl-3,4Ј,5-tricarboxylic acid) was synthesized under solvothermal conditions and structurally characterized by elemental analysis, powder X-ray diffraction analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound 1 features a 3D porous framework based on 1D rod-shaped * Dr. B.-M. Xu E-Mail: bingmei_xu666@126.com [a] The anticancer activity of compound 1 was advanced greatly after the encapsulation of 5-Fu.

Synthesis and Crystal Structure of Amino Acid Modified NDI Lanthanide Coordination Complex

“…The confocal laser scanning microscopy images of complex is recorded using CLSM (FV 1000) and the complex has regular blue clavate structure (Figure ). Three‐dimensional rare earth coordination polymers have important application both in smart drug carrier and anti‐cancer activity . This single crystal has strong blue fluorescence and stable 3D MOFs structure, it may be further applied in biological and medical research.…”

A New Samarium(III) Complex of Liriodenine: Synthesis, Crystal Structure, Antitumor Activity, and DNA Binding Study

“…Rare earth elements rank a special class in the transition metal elements. The rare earth metal complexes showed multiple application prospects, such as luminescent, magnetic, electrical, and biological activities . Rare earth cations ( Ln III ) are generally regarded as a kind of pseudo‐calcium(II) ions.…”