A three-dimensional Mn-based MOF as a high-performance supercapacitor electrode

Abstract

Developing new high-performance electrode materials for improving the energy density of supercapacitors is an important task. Herein, a new three-dimensional (3D) metal-orgainc frameworks (MOF) [Mn(BGPD)(H2O)2] (Mn-BGPD; BGPD = N,N′-bis(glycinyl)pyromellitic diimide)...

From 1D to 2D: Controllable Preparation of 2D Ni–MOFs for Supercapacitors

“…The performance is also comparable with those results of MOF-based electrodes in other literature (Table S1, Supporting Information). − Furthermore, as the current density increased to 20 A g –1 , the Ni-MOF-7:1 electrode has the best rate capability of 62% among all the samples (54% for Ni-MOF-9:1, 55% for Ni-MOF-3:1, and 51% for Ni-MOF-1:1). The electroactive sites of Ni-MOF-7:1 exhibit a higher level of participation.…”

A one-dimensional cobalt-based coordination polymer as a cathode material of lithium-ion batteries

“…2D and 3D porous CPs are also called metal-organic frameworks (MOFs), which have been widely applied in catalysis, energy storage, and separation. [25][26][27][28][29][30][31][32] MOFs/CPs as electrode materials of LIBs have been widely investigated due to their controllable structure, high specific surface area, and high porosity. [33][34][35][36][37][38][39] In 2007, Tarascon's research group 40 first reported that a 3D MOF (MIL-53(Fe)) shows excellent cycling stability as the cathode material of LIBs.…”

Sputtered binder-free Cu3N electrode materials for high-performance quasi-solid-state asymmetric supercapacitors

“…1,2 However, their low energy density limits their commercial applications, and electrode materials are the key factor determining the electrochemical performance of SCs. 3 Electrochemical double layer supercapacitors (EDLCs) commonly utilize carbon-based electrode materials to store charges via reversible ion adsorption at the electrode/ electrolyte interface, which usually suffers from low capacitance. 4,5 Unlike EDLCs, pseudocapacitors, as an alternative, can achieve boosted energy density, which originates from fast and reversible redox processes on the electrode surface or near-surface.…”