Clay mineralogical differences between eight soils in South Island, New Zealand, are related to differences in climate, vegetation, and formation time. Alteration of chlorite follows the sequence chlorite--*interlayered hydrous mica-~chlorite-swelling chlorite--*chlorite-vermiculite, with increased weathering leading to the destruction of the chloritic layers. Mica (muscovite) follows two alteration sequences depending on the overlying vegetation. Under tussock grassland the sequence is mica~mica-vernaiculite~mica-beidellite~beidellite. This sequence is also followed under beech forest, together with the sequence of mica-~vermiculite~beidellite, with pedogenic chlorite forming when the pH is > 4.5. All but one of the interstratified products (the interlayered hydrous mica) appear to be based on a 1:1 regular interlayering of the two components.Monosequences of soils, over which changes in soil properties can be attributed to variations in only one of the major soil-forming factors (Jenny, 1941), are valuable in indicating soil weathering processes, provided that the practical limitations of the monosequence approach are recognized (Crocker, 1952;Jenny, 1958; Walker, 1965;Campbell, 1975). The variety and complexity of the products of weathering transformations of micas and chlorites have been described by many workers (Rich, 1956;Gjems, 1960Gjems, , 1963Gjems, , 1970 Wilson, 1970;Campbell, 1975;De Coninck et al., 1975; Loveland & Bullock, t975;Moberg, 1976;Buurmann et al., 1976;Bain, 1977). The present paper describes some effects of the major soil-forming factors of vegetation and formation time upon the mineral transformations of some micas and chlorites by comparing the clay mineralogies of a number of New Zealand soils which have been arranged in pairs into two similar vegesequences and an approximate chronosequence. Results are integrated with those of an earlier climosequence study (Churchman, 1978) in order to elucidate the mechanisms of transformations of these minerals in soils.
SOILSThe soils studied are described in Table 1 in terms of the major factors influencing their formation and are arranged in approximate order of soil development. In addition, they are grouped for the purpose of deducing the effects of three main soil-forming factors (vegetation, time and climate) on mineral weathering, as indicated by the superscripts in the Table. One major factor varies within each group while other factors remain either largely constant or else show variations which are considered insignificant beside those of the major factor giving the name to the group.