2023
DOI: 10.1039/d2py01509a
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A tridentate phenoxy-phosphine (POP) divalent chromium complex and its reactivities in olefin polymerization

Abstract: We reported the synthesis and characterization of a Cr(ii) complex based on a tridentate phenoxy-phosphine ligand and studied its reactivities in ethylene and norbornene homopolymerization and ethylene copolymerization with norbornene or 1-octene.

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“…We have been interested in the synthesis of NBE and cyclopentene-associated COCs using Ti- and Cr- catalyzed olefin polymerizations and recently reported a unique binuclear Ni catalyst ( Cat1 , Figure B) for ethylene copolymerization with short-chain alkenoic acid comonomers . Herein, we report the NBE monomer effects on the chain walking olefin polymerization in terms of M w , chain end groups, branching, and the possible mechanistic scenarios in binuclear Cat1- catalyzed ethylene (E), propylene (P), and 1-hexene (1-H) copolymerization with NBE.…”
Section: Introductionmentioning
confidence: 99%
“…We have been interested in the synthesis of NBE and cyclopentene-associated COCs using Ti- and Cr- catalyzed olefin polymerizations and recently reported a unique binuclear Ni catalyst ( Cat1 , Figure B) for ethylene copolymerization with short-chain alkenoic acid comonomers . Herein, we report the NBE monomer effects on the chain walking olefin polymerization in terms of M w , chain end groups, branching, and the possible mechanistic scenarios in binuclear Cat1- catalyzed ethylene (E), propylene (P), and 1-hexene (1-H) copolymerization with NBE.…”
Section: Introductionmentioning
confidence: 99%