A turn-on fluorescent chemosensor based on acylhydrazone for sensing of Mg<sup>2+</sup> with a low detection limit

Hu, Jing‐Han; Li, Jianbin; Sun, You; Pei, Peng-Xiang; Qi, Jing

doi:10.1039/c7ra04462c

Cited by 24 publications

(5 citation statements)

References 41 publications

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“…Thus, the IR data also supported that –C=O, −OH, and −C=N groups participated in the formation of P -Mg 2+ complex. Thus, based on the obtained results and the reported works [ 7 , 18 , 19 ], the proposed probe P was most likely to coordinate with Mg 2+ in the mode as shown in Figure 5 . The binding with Mg 2+ blocked the photo-induced electron transfer (PET) mechanism and caused the fluorescence enhancement of P .…”

Section: Resultssupporting

confidence: 69%

“…Schiff-base compounds are effective to form stable complexes for different metal ions and anions. Based on these outstanding properties, they have been applied widely in the fields of catalysis, medicine, and fluorescent probes [ 18 , 19 , 20 ]. Beyond this, photo-induced electron transfer (PET) as a signal mechanism in photophysical processes has been broadly used [ 7 , 21 , 22 ].…”

Section: Introductionmentioning

confidence: 99%

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Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Chen

Wen

et al. 2021

Molecules

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A simple benzoyl hydrazine derivative P was successfully synthesized and characterized as Mg2+-selective fluorescent probe. The binding of P with Mg2+ caused an obvious fluorescence enhancement at 482 nm. The fluorescent, UV-vis spectra, 1H-NMR, and IR spectra confirmed the formation of P-Mg2+ complex, and the formation of a 1:1 stoichiometry complex was proved by Job’s plot and mass spectrometry. The recognition mechanism of P to Mg2+ was owing to the photoinduced electron transfer effect (PET). The fluorescent response was linear in the range of 0.9–4.0 µM with the detection limit of 0.3 µM Mg2+ in water–ethanol solution (1:9, v:v, pH10.0, 20 mM HEPES). In addition, the results of cell imaging of Mg2+ in Hl-7701 cells was satisfying.

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Section: Resultssupporting

confidence: 69%

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Chen

Wen

et al. 2021

Molecules

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“…These phenomena indicate that Mg 2+ is coordinated to the oxygen of -OH and the nitrogen of -NH in 1o. [46] The MS analysis further confirmed this prediction with a peak at m/z 779.0511 for the 1o-Mg 2+ complex, [1o + Mg 2+ À H + ] + , which also proved the formation of the 1o-Mg 2+ complex (Figure S6). According to the earlier results, the coordination mode of Mg 2+ with 1o was simulated.…”

Section: Recognition Mechanism For Mg 2+ and Zn 2+supporting

confidence: 60%

Synthesis and photophysical investigation of Schiff base as a Mg²⁺ and Zn²⁺ fluorescent chemosensor and its application

Mei

wentao

et al. 2023

Luminescence

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In view of the fluorescent switching properties and anti-fatigue properties of diarylethene, a diarylethene fluorescent chemosensor for the immediate detection of zinc ion (Zn 2+ ) and magnesium ion (Mg 2+ ) in acetonitrile was synthesized in this article.The structure of 1o was determined by performing spectroscopy and elemental analysis. The presence of Zn 2+ or Mg 2+ made the chemosensor 1o show an obvious "turn-on" fluorescent signal (bright yellow-green for Mg 2+ and bright cyan for Zn 2+ ).The fluorescent change caused by the 1:1 binding of 1o and Zn 2+ or Mg 2+ might be due to hindering the excited-state intramolecular proton transfer (ESIPT) process, which were bolstered by Benesi-Hildebrand analysis, Job's plot curves, proton nuclear magnetic resonance ( 1 H-NMR) titration and mass spectrometry. The limits of detection were acquired from the standard curve plots for Mg 2+ at 44.6 nM and for Zn 2+ at 14 nM. Based on the fluorescent behaviors, a logic gate was constructed with the emission intensity at 528/518 nm as output signal, the ultraviolet-visible (UV-vis) lights, Mg 2+ /Zn 2+ and EDTA as input signals. Exogenous Zn 2+ and Mg 2+ fluorescent bioimaging were performed on Hela cells with 1o, indicating its potential application in biodiagnostic analysis. In particular, 1o was manufactured into test paper, and Zn 2+ or Mg 2+ can be conveniently, efficiently and qualitatively identified by the fluorescent color variation of the test strips.

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“…The detection limits of the present probe are compared with the reported probes, as depicted in Table S2 (ESI†). 49–69…”

Section: Resultsmentioning

confidence: 99%

A tripodal imine-derived Fe(iii) complex for the fluorescence recognition of Mg(ii) via green emission: crystal structure, photophysical interactions and DFT studies

et al. 2023

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A turn-on fluorescent chemosensor based on acylhydrazone for sensing of Mg²⁺ with a low detection limit

Abstract: A novel highly selective chemosensor for Mg2+ ions based on the naphthalene group as the fluorophore has been designed and synthesized, which shows a fluorescence turn-on response from colorless to green for Mg2+ ions in DMSO–H2O solutions.

Cited by 24 publications

References 41 publications

Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Synthesis and photophysical investigation of Schiff base as a Mg²⁺ and Zn²⁺ fluorescent chemosensor and its application

A tripodal imine-derived Fe(iii) complex for the fluorescence recognition of Mg(ii) via green emission: crystal structure, photophysical interactions and DFT studies

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A turn-on fluorescent chemosensor based on acylhydrazone for sensing of Mg2+ with a low detection limit

Abstract: A novel highly selective chemosensor for Mg2+ ions based on the naphthalene group as the fluorophore has been designed and synthesized, which shows a fluorescence turn-on response from colorless to green for Mg2+ ions in DMSO–H2O solutions.

Cited by 24 publications

References 41 publications

Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Synthesis and Characterization of a Mg2+-Selective Probe Based on Benzoyl Hydrazine Derivative and Its Application in Cell Imaging

Synthesis and photophysical investigation of Schiff base as a Mg2+ and Zn2+ fluorescent chemosensor and its application

A tripodal imine-derived Fe(iii) complex for the fluorescence recognition of Mg(ii) via green emission: crystal structure, photophysical interactions and DFT studies

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Product

Resources

About

A turn-on fluorescent chemosensor based on acylhydrazone for sensing of Mg²⁺ with a low detection limit

Synthesis and photophysical investigation of Schiff base as a Mg²⁺ and Zn²⁺ fluorescent chemosensor and its application