A two-dimensional photoluminescent cadmium(II) coordination polymer containing a new coordination mode of pyridine-2,3-dicarboxylate: Synthesis, structure and molecular simulations for gas storage and separation applications

Semerci, Fatih; Yeşılel, Okan Zafer; Soylu, Mustafa Serkan; Keskin, Seda; Büyükgüngör, Orhan

doi:10.1016/j.poly.2012.10.009

Cited by 40 publications

(13 citation statements)

References 50 publications

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“…One of the primary foci of inorganic chemistry basic research in recent years has been the preparation, structural characterization, and properties measurements of crystalline coordination polymers containing divalent metal atoms. This genre of solid‐state materials has exhibited utility in hydrogen adsorption, molecular separations, ion exchange, heterogeneous catalysis for organic transformations, and as sensors for the detection of explosive compounds or substances of environmental concern . The striking aesthetic appeal of the underlying topologies of coordination polymers is also an undeniable impetus for continued investigation .…”

Section: Introductionmentioning

confidence: 99%

Zinc and Cadmium Diphenate Coordination Polymers with Conformationally Flexible Dipyridylamide Ligands

Martinez

LaDuca

2017

Zeitschrift anorg allge chemie

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Zinc and cadmium diphenate (dip, biphenyl‐2,2′‐dicarboxylate) coordination polymers containing conformationally flexible dipyridylamide ligands show diverse chain and layer topologies as determined by single‐crystal X‐ray diffraction. [Cd(dipH)2(bdin)]n (1) [bdin = N,N′‐(butane‐1,3‐diyl)diisonicotinamide] shows a simple 1D zigzag chain structure. {[Cd(dip)(pdin)(H2O)]·1.25H2O}n (2) [pdin = N,N′‐(propane‐1,3‐diyl)diisonicotinamide] shows bilayer slabs formed by interleaving of (4,4) rectangular grid layers. {[Zn2(dip)2(3‐pna)2]·3H2O}n (3) (3‐pna = 3‐pyridylnicotinamide) manifests a rare 4‐connected 1D ribbon topology. {[Cd(dip)(4‐ppbp)]·2H2O}n (4) [4‐ppbp = propane‐1,3‐diylbis(piperidine‐4,1‐diyl)bis(pyridin‐4‐ylmethanone)] shows a 3,5‐connected layer with (426)(42678) 3,5L2 topology. {[Zn4(dip)4(H2O)2(4‐ppbp)2]·12H2O}n (5) exhibits 2D 3,6‐connected layers with (43)2(466683) kgd topology featuring embedded R(8)A(2) classification 10‐membered water clusters. Compounds 1, 4, and 5 undergo violet or blue‐violet fluorescence upon ultraviolet irradiation. Thermal decomposition behavior of the new phases is also discussed.

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Section: Introductionmentioning

confidence: 99%

Zinc and Cadmium Diphenate Coordination Polymers with Conformationally Flexible Dipyridylamide Ligands

Martinez

LaDuca

2017

Zeitschrift anorg allge chemie

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“…This interest stems from their potential applications as functional materials such as gas storage, ion exchangers, catalysis, magnetism, and molecular sensing [22][23][24][25][26][27][28]. These compounds containing redox active ions of transition metals such as Fe, Co, Ni, Cu, Mn, Mo and V may have catalytic activity for reactions following a redox mechanism [29].…”

Section: Introductionmentioning

confidence: 99%

Investigation of the catalytic behavior of a Cu coordination polymer capped polyoxometalate as an oxidation catalyst

Farzaneh

Moghzi

2015

Reac Kinet Mech Cat

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A multifunctional organic-inorganic hybrid based on a Cu coordination polymer capped polyoxometalate (H 3 PMo 12 O 40 ) designated as compound 1 with [Cu I (4,4 0 -bipy)] 3 [PMo 10 VI Mo 2 V O 40 {Cu II (2,2 0 -bipy)}] formula was prepared using CuCl 2 Á2H 2 O, 4,4 0 -bipy, 2,2 0 -bipy and H 3 PMo 12 O 4 in water under hydrothemal conditions. The prepared compound 1 was characterized by FTIR, XRD and chemical analysis techniques. It was found that the compound successfully catalyzes the epoxidation of various alkenes such as diphenyl ethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene and oxidation of alkanes such as fluorene, adamantane, diphenylmethane, cyclohexane and cyclooctane, in acetonitrile with 20-99 % conversion and 53-100 % selectivity with tert-butyl hydroperoxide as oxidant under optimized condition. This heterogeneous catalyst could be easily recovered and reused after reaction without loss of activity.

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“…The rapid progress of organic-inorganic hybrid materials have received significant attention for their structural diversity [1][2][3] and fascinating properties with applications such as magnetism [4], gas storage [5], electrical conductivity [6], luminescent science [3,7] and catalysis [8]. The design of the bridging ligands is proved to be one of the most effective ways to manipulate the versatile structures of in the use a multifunctional Cu coordination polymer based on polyoxometalate as an efficient heterogeneous catalyst for the Knoevenagel condensation of a variety of aldehydes with malononitrile or ethyl cyanoacetate.…”

Section: Introductionmentioning

confidence: 99%

Multifunctional Cu(II) organic–inorganic hybrid as a catalyst for Knoevenagel condensation

Farzaneh

Maleki

Ghandi

2015

Reac Kinet Mech Cat

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In this study, organic-inorganic hybrid materials based on polyoxometalate and copper coordination polymer, [Cu I (4,4 0 -bipy)] 3 [PMo 10 VI Mo 2 V O 40 {Cu II (2,2 0 -bipy)}] designated as CuMo-CP(1), were prepared and characterized by various techniques including X-ray powder diffraction (XRD), infrared spectroscopy (FT-IR), and elemental analysis. It was found that the CuMo-CP(1) can be used as an efficient heterogeneous bifunctional acid-base catalyst for Knoevenagel condensation of aromatic aldehydes and cyclohexanone with malononitrile or ethyl cyanoacetate at 60°C in ethanol. Obtaining the corresponding Knoevenagel adduct in moderate to excellent conversion yields within 4 h is promising. The catalyst can be easily recovered from the reaction mixture and reused for three times without significant loss of activity.

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A two-dimensional photoluminescent cadmium(II) coordination polymer containing a new coordination mode of pyridine-2,3-dicarboxylate: Synthesis, structure and molecular simulations for gas storage and separation applications

Cited by 40 publications

References 50 publications

Zinc and Cadmium Diphenate Coordination Polymers with Conformationally Flexible Dipyridylamide Ligands

Zinc and Cadmium Diphenate Coordination Polymers with Conformationally Flexible Dipyridylamide Ligands

Investigation of the catalytic behavior of a Cu coordination polymer capped polyoxometalate as an oxidation catalyst

Multifunctional Cu(II) organic–inorganic hybrid as a catalyst for Knoevenagel condensation

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