2020
DOI: 10.3390/molecules25030593
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A Versatile Approach to Access Trimetallic Complexes Based on Trisphosphinite Ligands

Abstract: A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of four trisphosphinite ligands of formula [CH3C{(C6H4OR2)3], where R stands for Ph (1a), Xyl (1b, Xyl = 2,6-Me2-C6H3), iPr (1c), and Cy (1d). These polyfunctional phosphinites allowed us to investigate their coordination chemistry towards a range of late … Show more

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Cited by 4 publications
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References 63 publications
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