Thermodynamics - Fundamentals and Its Application in Science 2012
DOI: 10.5772/51383
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A View from the Conservation of Energy to Chemical Thermodynamic

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“…Such a system is in mechanical equilibrium with its surroundings because an infinitesimal change in the external pressure in either direction causes changes in volume in opposite directions. In either case the change is reversible in the thermodynamic sense (Gürses and Ejder-Korucu 2012). If, on the other hand, the external pressure differs measurably from the internal pressure, then change in the external pressure infinitesimally will not decrease it below the pressure of the gas, so it will not change the direction of the process.…”
Section: Introductionmentioning
confidence: 97%
“…Such a system is in mechanical equilibrium with its surroundings because an infinitesimal change in the external pressure in either direction causes changes in volume in opposite directions. In either case the change is reversible in the thermodynamic sense (Gürses and Ejder-Korucu 2012). If, on the other hand, the external pressure differs measurably from the internal pressure, then change in the external pressure infinitesimally will not decrease it below the pressure of the gas, so it will not change the direction of the process.…”
Section: Introductionmentioning
confidence: 97%