2024
DOI: 10.1021/acs.orglett.4c03278
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A Visible Light Photoredox Approach for Synthesizing Sulfone-Functionalized Cyclopropenes

Sourabh Biswas,
Manasi Mallick,
Gouri Nanda K S
et al.

Abstract: We have developed a tandem method essential for synthesizing sulfone-containing organic molecules, which has wideranging applications in agrochemicals, medicinal chemistry, and polymer science. This method involves a two-step process: an iodosulfonylated intermediate is formed initially, followed by elimination to regenerate the double bond, ultimately yielding sulfonecontaining cyclopropenes. Control studies have confirmed the intermediacy of iodo-sulfonylated cyclopropane within the reaction sequence. Additi… Show more

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