hereby declare that this thesis is my own work and, to the best of my knowledge, it neither contains materials previously published or written by any other person, nor has it been submitted for any degree/diploma or any other academic award anywhere before. I have used the originality checking service to prevent inappropriate copying.I also declare that all copyrighted material incorporated into this thesis is in compliance with the Indian Copyright Act, 1957Act, (amended in 2012 and that I have received written permission from the copyright owners for my use of their work. I hereby grant permission to IISER Kolkata to store the thesis in a database which can be accessed by others.