A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Shao, Zhen-Wu; Xiong, Chaozhi; Yang, Jiajie; Mei, Zhewei; Xiong, Li; Wu, Wenjing; Liu, Chong

doi:10.1039/d4cc03895a

Chem. Commun.

2024

DOI: 10.1039/d4cc03895a

|View full text |Cite

A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Zhen-Wu Shao,

Chaozhi Xiong,

Jiajie Yang

et al.

Abstract: A highly crystalline and robust Zr-hydroxamate MOF was made from a pyrazine-derived ligand. Featuring abundant chelating sites which were readily metalated with a high Pd loading, the MOF became a versatile and recyclable Suzuki–Miyaura catalyst.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

2025

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 36 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Hydroxamate‐Based Metal‐Organic Frameworks

Sugamata

2024

Chemistry A European J

View full text Add to dashboard Cite

This mini‐review focuses on recent developments in hydroxamate‐based metal–organic frameworks (MOFs), which exhibit unique structures and properties distinct from those of carboxylate‐based MOFs. Hydroxamates (RCONHO−), which are bioisosteres of carboxylates (RCOO−), form MOFs with novel structural motifs and functionalities. In this review, synthetic strategies, structural characteristics, and functional applications of key examples of hydroxamate‐based MOFs are described, providing insights into the influence of the hydroxamate ligand on the MOF properties compared to the carboxylate‐based analogues.

show abstract

Hydroxamate‐Based Metal‐Organic Frameworks

Sugamata

2024

Chemistry A European J

View full text Add to dashboard Cite

show abstract

Recyclable polyethylenimine based polymer for selective Pd(II) recovery and Suzuki reaction: Waste to treasure tactics

Peng,

Zeng,

Zhong

et al. 2025

Separation and Purification Technology

View full text Add to dashboard Cite

Charge-Tunable Bismuth-Hydroxamate Metal–Organic Frameworks for Photocatalytic Cr(VI) Mitigation

Xiong,

Shao,

Zhang

et al. 2024

Crystal Growth & Design

View full text Add to dashboard Cite

This study presents three bismuth-hydroxamate metal−organic frameworks (MOFs), namely, SUM-90A/B/C (SUM = Sichuan University Materials), prepared from Bi 3+ and the same bridging ligand (1,4-benzenedihydroxamic acid). By varying the synthetic conditions, the charge states of the framework backbones and the coordination environments of the Bi 3+ centers were finetuned, resulting in distinct structures and properties. The performances of MOFs as heterogeneous photocatalysts for Cr(VI) mitigation were comparatively studied, using both theoretical and experimental methods, and they exhibited remarkable kinetic stability in aqueous media and varied electronic structures. Specifically, SUM-90C, with an experimental band gap of 1.92 eV, was identified as a promising photocatalyst that could effectively convert Cr(VI) within 4 h and retain 96% of its capability over 3 cycles.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Abstract: A highly crystalline and robust Zr-hydroxamate MOF was made from a pyrazine-derived ligand. Featuring abundant chelating sites which were readily metalated with a high Pd loading, the MOF became a versatile and recyclable Suzuki–Miyaura catalyst.

Cited by 3 publications

References 36 publications

Hydroxamate‐Based Metal‐Organic Frameworks

Hydroxamate‐Based Metal‐Organic Frameworks

Recyclable polyethylenimine based polymer for selective Pd(II) recovery and Suzuki reaction: Waste to treasure tactics

Charge-Tunable Bismuth-Hydroxamate Metal–Organic Frameworks for Photocatalytic Cr(VI) Mitigation

Contact Info

Product

Resources

About