AB-type monomer of polyhedral oligomeric silsesquioxane

Nakano, Taishi; Imoto, Hiroaki; Naka, Kensuke

doi:10.1039/d3qi02674d

Inorg. Chem. Front.

2024

DOI: 10.1039/d3qi02674d

|View full text |Cite

AB-type monomer of polyhedral oligomeric silsesquioxane

Taishi Nakano,

Hiroaki Imoto,

Kensuke Naka

Abstract: Polyhedral oligomeric silsesquioxanes (POSSs) are crucial building blocks for the fabrication of organic-inorganic hybrid materials. Bifunctional POSS monomers have been developed using incompletely condensed POSS (IC-POSS) for main-chain-type POSS polymers....

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Open and Closed Cage Silsesquioxane Dimers

Yonezawa,

Naka,

Imoto

2024

ChemPlusChem

View full text Add to dashboard Cite

Polyhedral oligomeric silsesquioxane (POSS) is an organic‐inorganic hybrid molecule with two structural variations, closed‐ and open‐cage configurations, referred to as completely condensed POSS (CC‐POSS) and corner‐opened POSS (CO‐POSS), respectively. In this study, we synthesized 12 dimers by combining CC‐ and CO‐POSS variants decorated with isobutyl or phenyl substituents to explore their structure‐property relationships. The choice of substituents, both at the cage vertices and open sites, significantly affected the thermal and optical properties of the materials. Modifying the substituents on CO‐ and CC‐POSS, which are isomers, led to significant alterations in the material properties. Notably, isomer‐bearing carbazole substituents exhibited a substantially higher quantum yield (0.32) than its counterpart isomer (0.13), underscoring the crucial role of structural nuances in determining material performance. These results offer valuable insights for the design of novel silsesquioxane‐based materials.

show abstract

Open and Closed Cage Silsesquioxane Dimers

Yonezawa,

Naka,

Imoto

2024

ChemPlusChem

View full text Add to dashboard Cite

show abstract

Designing strategically functionalized hybrid porous polymers with octavinylsilsesquioxane/dibenzo[g,p]chrysene/benzo[c]-1,2,5-thiadiazole units for rapid removal of Rhodamine B dye from water

Hsiao,

Elewa,

Mohamed

et al. 2024

Colloids and Surfaces A: Physicochemical and Engineering Aspect

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

AB-type monomer of polyhedral oligomeric silsesquioxane

Abstract: Polyhedral oligomeric silsesquioxanes (POSSs) are crucial building blocks for the fabrication of organic-inorganic hybrid materials. Bifunctional POSS monomers have been developed using incompletely condensed POSS (IC-POSS) for main-chain-type POSS polymers....

Cited by 2 publications

References 62 publications

Open and Closed Cage Silsesquioxane Dimers

Open and Closed Cage Silsesquioxane Dimers

Designing strategically functionalized hybrid porous polymers with octavinylsilsesquioxane/dibenzo[g,p]chrysene/benzo[c]-1,2,5-thiadiazole units for rapid removal of Rhodamine B dye from water

Contact Info

Product

Resources

About