Abiotic and biotic degradations of a LDPE blend in soil of South Brazil landfill

Abstract

Polyethylene degrades slowly when discarded in the environment and exposed to natural weathering. A solution to this problem is the incorporation of additives to accelerate its biodegradation. In the present study, a biodegradable low-density polyethylene (LDPE) blend was obtained by the mixture of LDPE with a biodegrading additive (8% w/w) and the effect of accelerated weathering on biodegradation process was assessed. Chemical, mechanical, thermal, and morphological properties of non-aged and aged samples were studied. Results showed that aging process caused changes on structural characteristics (insertion of functional groups), morphological (appearance of micro-cracks and increased roughness), mechanical (greater stiffness and loss of plasticity) and thermal (lower degree of crystallinity and thermal stability) properties. The presence of biodegrading additive contributed to aging process, since polar functional groups were inserted into additive exposed to soil underwent greater degradation than their non-aged counterparts. CO 2 production of aged LDPE blend demonstrated that accelerated weathering influences biodegradation process. In this work, due to availability of O 2 gas, aerobic microorganisms can be the main responsible by the material deterioration, leading to production of microbial biomass, CO 2 and H 2 O. Thus, the results of biodegradation (166 days) obtained in this work are promising, once it was reached a natural soil from South Brazil landfill.

From plastic mulching to microplastic pollution : An effect assessment of microplastics in the soil-plant system

“…This might be attributed to the property of LDPE polymers. LDPE has a linear hydrocarbon structure with stable C=C double bonds, which are relatively resistant to degradation under natural field conditions (Dilara and Briassoulis, 2000;Miranda et al, 2020). As a result, the SOC of each LDPE-MPs treatment remained stable during the experiment.…”