An increasing number of papers are focusing on integrating psychological aspects into the typical discrete choice models. The majority of these studies account for several latent effects, but they mainly focused on the direct effect of attitudes, perception, and norms in the discrete choice. None of them consider the effect of intention and its role as mediator between those psychological effects and the choice, as implied in the Theory of Planned Behavior. In this paper we contribute to the literature in this field by specifically studying the direct effect of the intention on the actual behavior, while attitude, social norms, and perceived behavioral control affect the intention to behave in a given way. We apply a hybrid choice model to study the departure time choice. For this, we used data from Danish commuters in the morning rush hours in the Greater Copenhagen Area. We found a significant effect of the intention to arrive at work on time on the departing time choice, and also a significant effect of the lower level mediators on the intention. Furthermore, the attitude toward short travel time was found to be significant. Finally, in terms of forecasting, we found that individuals who have a strong intention to be at work on time will be less likely to reschedule their departure time. This suggests that campaigns targeting the working culture could affect the subject norms among colleagues, which in turn influence individuals' intention to be on time or to reschedule to a less congested time slot.