“…In the presence of 23 titanocene dichloride, the signal attributed to tetrafluoroborate counter ion appears also down shielded at -152.55 ppm which highlights the existence of some type of interaction between the organometallic complex and the counter anion. In fact, metallocene Ti(IV) fluoride complexes can be prepared from the corresponding chloride or alkyl congeners by halogen exchange reaction with AgBF 4 or BF 3 [33] Finally, when the 19 F-NMR spectrum of the mixture titanocene-DBT-ILBF 4 is recorded the signal appears downfield shifted at -152.52 ppm. These results reflect the existence of a synergic effect in the interaction of DBT and titanocene dichloride with the tetrafluoroborate anion in the ionic liquid and allow us to propose the establishment of a three compounds interaction system (see Fig.…”