Trapping of microspheres with a single focused laser beam is usually limited to materials with relative refractive indexes slightly larger than one. We show that directional light scattering can be employed to optically trap high-index materials. For this purpose, we propose a material platform to achieve zero backward scattering (ZBS), also known as the first Kerker condition, in a composite media containing spherical inclusions of silica embedded in a SiC microsphere. By tuning the volume filling fraction of inclusions and the microsphere radius, stable trapping can be achieved, provided that ZBS is combined with the condition for destructive interference between the fields reflected at the external and internal interfaces of the microsphere when located at the focal point. We show that our proposal also holds even in the presence of a significant amount of spherical aberration, which is a common condition in most optical tweezers setups. In this case, achieving ZBS is essential for trapping high-index materials.