2018
DOI: 10.1364/ao.57.002102
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Absolute frequency measurement of molecular iodine hyperfine transitions at 647  nm

Abstract: We report absolute frequency measurements of molecular iodine P(46) 5-4 a, a, and a hyperfine transitions at 647 nm with a fiber-based frequency comb. The light source is based on a Littrow-type external-cavity diode laser. A frequency stability of 5×10 at a 200 s integration time is achieved when the light source is stabilized to the P(46) 5-4 a line. The pressure shift is determined to be -8.3(7)  kHz/Pa. Our determination of the line centers reached a precision of 21 kHz. The light source can serve as a ref… Show more

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Cited by 7 publications
(3 citation statements)
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“…Pressure shifts of iodine lines are found to be in the range of 5 to 9 kHz Pa −1 . [26][27][28][29][30][31] With the vapor pressure temperature dependence of iodine being 14.9 Pa K −1 at about 45°C 33 (and increasing for higher temperatures), the pressure shift as a function of cell temperature can be estimated to be less than 10 cm s −1 K, consistent with FTS measurements. 22 This means that, by maintaining a temperature stability of better than 1 K, a 10 cm s −1 accuracy of the iodine spectrum can be achieved.…”
Section: Discussionsupporting
confidence: 75%
See 1 more Smart Citation
“…Pressure shifts of iodine lines are found to be in the range of 5 to 9 kHz Pa −1 . [26][27][28][29][30][31] With the vapor pressure temperature dependence of iodine being 14.9 Pa K −1 at about 45°C 33 (and increasing for higher temperatures), the pressure shift as a function of cell temperature can be estimated to be less than 10 cm s −1 K, consistent with FTS measurements. 22 This means that, by maintaining a temperature stability of better than 1 K, a 10 cm s −1 accuracy of the iodine spectrum can be achieved.…”
Section: Discussionsupporting
confidence: 75%
“…This model has been experimentally verified for multiple transitions, each at different wavelengths (534, 535, 548, 560, 647, and 671 nm) using LFCs. [26][27][28][29][30][31] The deviations to the model range from −3.6 to 2.2 MHz (corresponding to better than 2.5 m s −1 ) with measurement uncertainties typically in the range of 10 to 25 kHz (corresponding to better than 2 cm s −1 ). Although this shows that the model does not (yet) exhibit accuracy on the sub m s −1 level, the spectrum of iodine itself provides an accurate standard as illustrated by its recommended use as a practical realization of the meter by the Comité international des poids et mesures (CIPM).…”
Section: Discussionmentioning
confidence: 99%
“…For example. iodine cells have long been used as a frequency reference in the infra-red due to the large number of well-characterized spectral lines in that range [25,26]. There are also examples of one atomic species being used as a frequency reference for another in precision measurement experiments, for example in [27].…”
Section: Introductionmentioning
confidence: 99%