INTRODUCTIONThis volume is one of a set which is concerned with all aspects of thermal radiation phenomena in heated air, over a wide range of temperature and density. Thermal radiation phenomena are meant to be those which arise due to or are related to, the passage of electromagnetic energy through an atmosphere of some type when significant interaction occurs between the radiation stream and the atmosphere. It is usually implied that some type of partial thermal equilibrium is produced by this interaction, although not a complete one, of course. In the case of complete thermal equilibrium, there can be only an uninteresting homogeneous system with no net transport of radiation at all. Radiation is a significant mode of energy transfer in all gases at sufficiently high temperatures, and in many situations at low temperatures as well. Since radiative energy transfer is controlled by the absorption coefficient which is, in turn determined by the microscopic atomic and molecular, and the statistical/thermodynamic properties of the medium, much of these volumes are concerned with these underlying properties. In particular, after a brief introduction to the theory of radiative transfer limited to conditions of local thermodynamic equilibrium, the present volume is mainly concerned with the detailed application of the basic quantum theory of radiation to real atomic and molecular systems. The transfer problem only reappears occasionally to guide this application into the practical channels which constitute the raison d'etre of the book.Although radiation transport is now of wide interdisciplinary application, most of its basic developments were made in an astrophysical milieu. Some of its contemporary applications are in stellar, solar and planetary atmospheres and aeronomy, in meteor, missile and rocket re-entry phenomena, in F combustion physics and chemistry, and in plasma and weapons physics.Towards very high temperatures there are fewer contributing effects and therefore the situation is conceptually somewhat simpler. Fig. 1.1 illustrates some significant subdivisions and interrelations towards the high-temperature limit of our considerations. As one progresses downwards in temperature, the effects and interactions proliferate and become, at our present state of knowledge, more fragmented and diverse, so that we will not attempt an illustration in this case,A large fraction of the work dating from World War II on specific problems in the above fields of application has been motivated by defense needs and financed by government contracts. As a result, much of the literature on the subject is comprised of unpublished and therefore unrefereed contract reports which are not universally available to the scientific community. Much of the work described in this "grey" literature (Goody, 1964) is important, but some obscurities and errors in an already complex field have propagated through these reports. Other problems due to the particular history of this field have also occurred. For example, a perusal of the reports...