The gas-phase mass transfer characteristics in a counter airflow shear rotating packed bed (CAS-RPB) were studied. The gas volumetric mass transfer coefficient (k y a e ) was characterized with the physical absorption system NH 3 -H 2 O and the effective interfacial area (a e ) was determined by the chemical absorption system CO 2 -NaOH, and then the gas-phase mass transfer coefficient (k y ) was obtained. The gas-phase mass transfer characteristics in the CAS-RPB were compared with those in the rotating packed bed with split packing (SP-RPB) under the same operating conditions. The experimental results indicated that the k y a e , a e , and k y for counter-rotation of adjacent packing rings in the CAS-RPB and SP-RPB were larger than those for co-rotation, and the k y a e , a e , and k y for counter/co-rotation in the CAS-RPB were respectively greater compared with those for counter/co-rotation in the SP-RPB. This confirmed that the CAS-RPB can further intensify the gas-phase mass transfer process compared to the SP-RPB. Moreover, the correlative expressions for the k y a e , a e , and k y in the CAS-RPB and SP-RPB were obtained and were in close agreement with the experimental results.