Supercapacitors (SCs)impedance modeling represents one important key to get information for SCs health monitoring and simulation. As a matter of fact, SCs behavior is dependent on various parameters such as pore size distribution of electrodes, electrolyte state, temperature, aging… We propose in this work to model supercapacitor taking into account physical considerations. Basing on theory on homogenous structure impedance, we define in first time, single pore (SP) model using uniform size of pores distribution. In the second step, we attempt to generalize this circuit model considering an electrode with different pores sizes or different penetrabilities of the pores. This model called multi-pore (MP) model (or multi-penetrability model) has been developed by our laboratories. This model allows analyzing the behavior of supercapacitor by modelling each group of electrode pores as a branch of an electrical equivalent circuit. This paper is the first in literature to give a simple and reproducible method for MP model parameters identification. The validity of the identification method will also be verified at different supercapacitor aging rates thanks to experimental aging tests.