The current research concerns the group acceptance sampling plan in the case where (i) the lifetime of the items follows the Marshall–Olkin Kumaraswamy exponential distribution (MOKw-E) and (ii) a large number of items, considered as a group, can be tested at the same time. When the consumer’s risk and the test terminsation period are defined, the key design parameters are extracted. The values of the operating characteristic function are determined for different quality levels. At the specified producer’s risk, the minimum ratios of the true average life to the specified average life are also calculated. The results of the present study will set the platform for future research on various nano quality level topics when the items follow different probability distributions under the Marshall–Olkin Kumaraswamy scheme. Real-world data are used to explain the technique.