Pathways and enzymes offatty acid synthasemediated, long-even-chain (generally C16-C20) fatty add synthesis are well studied, and general metabolism involved in short-chain (Cs-C7) fatty acid biosynthesis is also understood.In contrast, mechanism of medinm-chain (C#-C14) Mechanisms for synthesis oflong-chain fatty acids (lcFAs) in plants are well studied (1). In contrast, metabolism leading to the biosynthesis of mcFAs is not well understood (4, 5), particularly that catalyzing the formation of branched and odd-length mcFAs. Straight, iso-, and antiso-branched, oddand even-length scFAs are synthesized via modified branched-chain amino acid (bcAA) metabolism in tobacco