Acetylacetonate Ruthenium Nitrosyls: A Gateway to Nitric Oxide Release in Water under Near-Infrared Excitation by Two-Photon Absorption

Labra-Vázquez, Pablo; Mudrak, Vladyslav; Tassé, Marine; Mallet-Ladeira, Sonia; Sournia-Saquet, Alix; Malval, Jean-Pierre; Lacroix, Pascal G.; Malfant, Isabelle

doi:10.1021/acs.inorgchem.3c03355

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2024

2025

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Cited by 3 publications

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“…39 In the context of the pushpull strategy towards efficient NO • release ((i) in Scheme 1), we have investigated various substituents π-conjugated to the terpyridine. [40][41][42][43] By contrast, the synthetic procedures afferent to the antenna strategy ((ii) in Scheme 1) require non-conjugated substituents and therefore, have to be completely reconsidered.…”

Section: Synthesis and Characterizationmentioning

confidence: 99%

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Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna

Mudrak,

Lacroix,

Tassé

et al. 2024

Dalton Trans.

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Section: Synthesis and Characterizationmentioning

confidence: 99%

“…Detailed procedure of kinetic studies was described in our previous works. 43,59 Data on NO • photorelease at 300 and 365 nm for C and AC are presented in ESI. † Fluorescence spectra were recorded on a Jobin Yvon Fluoromax 4 Spectrofluorimeter.…”

Section: Materials and Equipmentmentioning

confidence: 99%

Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna

Mudrak,

Lacroix,

Tassé

et al. 2024

Dalton Trans.

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Generation and Application of Reactive Oxygen Radicals in Cancer Treatment

Patial,

Sharma,

Sharma

et al. 2024

ChemistrySelect

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Reactive oxygen species (ROS) play a dual role in cancer, influencing both tumor growth and regression. Their intricate involvement in cellular processes underscores the necessity of maintaining a delicate ROS balance for normal cellular function. Intriguingly, while ROS contribute to tumor progression, they also exhibit the potential to selectively kill cancer cells. Emerging therapeutic strategies focus on modulating ROS levels within cancer cells, considering the type of radicals generated, their site of formation, and concentration gradients. This review delves into recent advancements in understanding the impact of ROS on the tumor microenvironment and cancer treatment. By exploring the interplay between ROS dynamics and therapeutic outcomes, this study provides a comprehensive perspective on the pivotal role of oxygen‐related free radicals in cancer therapy and highlights the innovative approaches and insights shaping this rapidly evolving field.

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Electronic structure of light-induced nitrosyl linkage isomers revealed by X-ray absorption spectroscopy at Ru L3,2-edges

Mikhailov,

Deresz,

Tiognou

et al. 2025

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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Acetylacetonate Ruthenium Nitrosyls: A Gateway to Nitric Oxide Release in Water under Near-Infrared Excitation by Two-Photon Absorption

Cited by 3 publications

References 72 publications

Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna

Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna

Generation and Application of Reactive Oxygen Radicals in Cancer Treatment

Electronic structure of light-induced nitrosyl linkage isomers revealed by X-ray absorption spectroscopy at Ru L3,2-edges

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