2023
DOI: 10.1016/j.apsusc.2022.156248
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Achieving efficient toluene mineralization over ordered porous LaMnO3 catalyst: The synergistic effect of high valence manganese and surface lattice oxygen

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Cited by 27 publications
(9 citation statements)
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“…The Mn 2p spectrum shows the valence state transition of Mn 4+ /Mn 3+ , which indicates that the chemical activity of the Mn electron pair is crucial for the formation of SO 4 ˙ − by PMS (eqn (1) and (2)). 55–57 PMS oxidizes Mn 3+ to Mn 4+ , and Mn 4+ is reduced to Mn 3+ by free radicals produced by PMS. With an increase in current, eqn (3) occurs preferentially, and the production of SO 5 ˙ − is maintained at a high level, which eventually leads to the efficient removal of LFX (eqn (4)–(8)).…”
Section: Resultsmentioning
confidence: 99%
“…The Mn 2p spectrum shows the valence state transition of Mn 4+ /Mn 3+ , which indicates that the chemical activity of the Mn electron pair is crucial for the formation of SO 4 ˙ − by PMS (eqn (1) and (2)). 55–57 PMS oxidizes Mn 3+ to Mn 4+ , and Mn 4+ is reduced to Mn 3+ by free radicals produced by PMS. With an increase in current, eqn (3) occurs preferentially, and the production of SO 5 ˙ − is maintained at a high level, which eventually leads to the efficient removal of LFX (eqn (4)–(8)).…”
Section: Resultsmentioning
confidence: 99%
“…explains the role of high valence manganese and surface lattice oxygen in the performance of LaMnO 3 towards the combustion of toluene. Figure 6 briefly explain the catalytic mechanism involved in the oxidation of toluene on the surface of LaMnO 3 [123] …”
Section: Methods For Vocs Removalsmentioning
confidence: 99%
“…Figure 6 briefly explain the catalytic mechanism involved in the oxidation of toluene on the surface of LaMnO 3 . [123] Layered manganese oxide was prepared via the reaction of KMnO 4 and Ammonium oxalate to study the effect of water in the adsorption of formaldehyde. This experiment was conducted at different temperatures and Wang et al [124] reported three classes of water (adsorbed H 2 O, interlayer H 2 O and hydroxyl) on the adsorbent which has helped the adsorption of formaldehyde, and it was established that the higher the water content the better the activity it has.…”
Section: Metal Oxidesmentioning
confidence: 99%
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“…Using plant’s absorption and physical absorption methods to remove formaldehyde is slow, non-specific, and less efficient. ,,, Catalytic oxidization is one of the chemical methods for formaldehyde decomposition. However, the complete decomposition of formaldehyde by catalytic oxidization creates ozone and other harmful chemicals. , Recently, it has been reported that the mineralization of volatile organic compounds can be achieved by increasing the catalytic activity of photothermal catalysts through surface lattice oxygen activation. , However, this method is mostly used for the removal of toluene and no application has been found for formaldehyde removal yet …”
Section: Introductionmentioning
confidence: 99%