The development of polymeric composites that possess both exceptional electromagnetic interference shielding effectiveness (EMI SE) and high absorption capacity has always been appealing, yet it continues to pose a significant challenge. To this end, we disclose a hollow and spherical shielding unit that could achieve “absorption‐reflection‐attenuation” process for incident electromagnetic (EM) wave, which was fabricated through decorating Ni nanoparticles onto rGO hollow microspheres by virtue of Pickering emulsification method followed by thermal annealing. With integrated magnetic and electric parts, the consequent shielding composite by assembling these microspheres into PDMS displayed not only a favorable EMI SE of 44 dB across the entire x‐band, but also significantly improved absorption performance that has exceeded 95% of the total SE. Moreover, the power coefficient of absorption (A) is up to 0.73 at the pyrolysis temperature of 550°C. Such admirable performance is mainly attributed to the synergistic effect of conductive rGO walls, magnetic Ni nanoparticles, as well as the unique spherical architecture, which has enabled more efficient capture and attenuation of EM waves. Herein, this research has highlighted the development of polymeric composites for high‐performance EMI shielding applications.Highlights
Reflection‐absorption‐integrated shielding compartment was designed.
Decorating magnetic Ni nanoparticles onto rGO hollow microspheres.
High EMI SE with enhanced absorption ability was acquired.
Unique structure generating synergistic effect on EMI shielding