Acid hydrolysis products of DDD and DDT precursors

Jensen, Bruce L.; Counsell, Raymond E.

doi:10.1021/jo00944a056

J. Org. Chem.

1973

DOI: 10.1021/jo00944a056

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Acid hydrolysis products of DDD and DDT precursors

Bruce L. Jensen¹,

Raymond E. Counsell²

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Cited by 5 publications

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Rearrangement of 1‐aryl‐2,2‐Dichloro‐1‐Alkanones and 1‐Aryl‐2,2‐Dichloro‐1‐Alkanols with Methylmagnesium Iodide

Kimpe¹,

Verhé²,

Buyck³

et al. 1979

Bulletin des Soc Chimique

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sium iodide in ether under reflux into highly sterically hindered alkohols. The mechanism proceeds by a pseudo pinacol type rearrangement of the initially formed carbonyl adduct. The mechanism of the rearrangement was proven by the synthesis of authentic reaction intermediates. The rearrangement was also extended to l-aryl-2,2-dichloro-l-alkanols which behaved analogously towards methylmagnesium iodide.l-Aryl-2,2-dichloro-l-alkanones were shown to rearrange with methyl magne-

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Rearrangement of 1‐aryl‐2,2‐Dichloro‐1‐Alkanones and 1‐Aryl‐2,2‐Dichloro‐1‐Alkanols with Methylmagnesium Iodide

Kimpe¹,

Verhé²,

Buyck³

et al. 1979

Bulletin des Soc Chimique

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ChemInform Abstract: SAURE HYDROLYSENPRODUKTE VON DDD‐ UND DDT‐VORSTUFEN

Jensen¹,

Counsell²

1973

Chemischer Informationsdienst

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Kinetic studies and improved reaction conditions for the halogen shift rearrangments of aryldihalopropanols

1978

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Acid hydrolysis products of DDD and DDT precursors

Cited by 5 publications

References 4 publications

Rearrangement of 1‐aryl‐2,2‐Dichloro‐1‐Alkanones and 1‐Aryl‐2,2‐Dichloro‐1‐Alkanols with Methylmagnesium Iodide

Rearrangement of 1‐aryl‐2,2‐Dichloro‐1‐Alkanones and 1‐Aryl‐2,2‐Dichloro‐1‐Alkanols with Methylmagnesium Iodide

ChemInform Abstract: SAURE HYDROLYSENPRODUKTE VON DDD‐ UND DDT‐VORSTUFEN

Kinetic studies and improved reaction conditions for the halogen shift rearrangments of aryldihalopropanols

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