Acidity and pH of DES-like mixtures and the possibilities of their determination

Jančíková, Veronika; Majová, Veronika; Jablonský, Michal

doi:10.1016/j.molliq.2023.123728

Journal of Molecular Liquids

2024

DOI: 10.1016/j.molliq.2023.123728

|View full text |Cite

Acidity and pH of DES-like mixtures and the possibilities of their determination

Veronika Jančíková,

Veronika Majová,

Michal Jablonský

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 70 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Enhancing 5‐Hydroxymethylfurfural Production from Fructose Using Triethylbenzylammonium Chloride‐Based Acidic Deep Eutectic Solvents: Optimization and Acidity Impact

Song,

Yuan,

Mai

et al. 2024

ChemPlusChem

View full text Add to dashboard Cite

5‐Hydroxymethylfurfural (5‐HMF) is an important biomass‐based platform compound that links biomass feedstocks with petrochemical refinery products. In this work, we developed a novel approach using TEBAC‐based acidic deep eutectic solvents (ADESs) to synthesize 5‐HMF through the dehydration of fructose. Our approach demonstrates significant improvements in both 5‐HMF yield and process efficiency compared to conventional solvent systems. Under optimal experimental conditions (90°C, 4.5 h), a maximum 5‐HMF yield of 97.77±3.20% was achieved at a TEBAC:acetic acid ratio of 2:3 with 1 wt% fructose loading. Notably, our system inhibits the formation of by‐products such as levulinic acid (LA) and formic acid (FA), which are commonly detected in other dehydration processes. Additionally, higher 5‐HMF yields of 76.67±0.33% and 73.51±1.14% were achieved with 10 wt% and 20 wt% fructose loadings, respectively, further highlighting the scalability of the process. The acidity of ADESs was found to significantly affect the dehydration rate and yield, as demonstrated through Hammett's acidity function analysis. The key innovation of our study lies in the strategic selection of hydrogen bond donors and acceptors in the DES, enabling both high efficiency and selectivity in 5‐HMF production. These findings provide a promising pathway for large‐scale biomass conversion with reduced by‐product formation.

show abstract

Enhancing 5‐Hydroxymethylfurfural Production from Fructose Using Triethylbenzylammonium Chloride‐Based Acidic Deep Eutectic Solvents: Optimization and Acidity Impact

Song,

Yuan,

Mai

et al. 2024

ChemPlusChem

View full text Add to dashboard Cite

show abstract

Harnessing two-dimensional magnetic Poly(deep eutectic solvents) for matrix solid-phase dispersion extraction of polyphenols from roselle: Promoting antiphotoaging strategy

Wang,

Li,

Wang

et al. 2024

Chemical Engineering Journal

View full text Add to dashboard Cite

Density, acidity and theoretical calculation of hydrophobic deep eutectic solvents formed by amide and lactic acid

Ma,

Xu,

Wei

et al. 2024

Journal of Molecular Liquids

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Acidity and pH of DES-like mixtures and the possibilities of their determination

Cited by 3 publications

References 70 publications

Enhancing 5‐Hydroxymethylfurfural Production from Fructose Using Triethylbenzylammonium Chloride‐Based Acidic Deep Eutectic Solvents: Optimization and Acidity Impact

Enhancing 5‐Hydroxymethylfurfural Production from Fructose Using Triethylbenzylammonium Chloride‐Based Acidic Deep Eutectic Solvents: Optimization and Acidity Impact

Harnessing two-dimensional magnetic Poly(deep eutectic solvents) for matrix solid-phase dispersion extraction of polyphenols from roselle: Promoting antiphotoaging strategy

Density, acidity and theoretical calculation of hydrophobic deep eutectic solvents formed by amide and lactic acid

Contact Info

Product

Resources

About