The
formation of liquid cloud droplets from aerosol particles
in
the Earth atmosphere is still under debate particularly because of
the difficulties to quantify the importance of bulk and surface effects
in these processes. Recently, single-particle techniques have been
developed to access experimental key parameters at the scale of individual
particles. Environmental scanning electron microscopy (ESEM) has the
advantage to provide in situ monitoring of the water uptake of individual
microscopic particles deposited on solid substrates. In this work,
ESEM was used to compare droplet growth on pure ammonium sulfate (NH4)2SO4 and mixed sodium dodecyl sulfate/ammonium
sulfate (SDS/(NH4)2SO4) particles
and to explore the role of experimental parameters, such as the hydrophobic–hydrophilic
character of the substrate, on this growth. With hydrophilic substrates,
the growth on pure salt particles was strongly anisotropic, but this
anisotropy was suppressed by the presence of SDS. With hydrophobic
substrates, it is the wetting behavior of the liquid droplet that
is impacted by the presence of SDS. The wetting behavior of the pure
(NH4)2SO4 solution on a hydrophobic
surface shows a step-by-step mechanism that can be attributed to successive
pinning–depinning phenomena at the triple-phase line frontier.
Unlike the pure (NH4)2SO4 solution,
the mixed SDS/(NH4)2SO4 solution
did not show such a mechanism. Therefore, the hydrophobic–hydrophilic
character of the substrate plays an important role in the stability
and dynamics of the liquid droplets’ nucleation by water vapor
condensation. In particular, hydrophilic substrates are not suited
for the investigation of the hygroscopic properties (deliquescence
relative humidity (DRH) and hygroscopic growth factor (GF)) of particles.
Using hydrophobic substrates, data show that the DRH of (NH4)2SO4 particles is measured within 3% accuracy
on the RH and their GF could indicate a size-dependent effect in the
micrometer range. The presence of SDS does not seem to modify the
DRH and GF of (NH4)2SO4 particles.
This study shows that the water uptake on deposited particles is a
complex process but, once carefully taken into account, ESEM is a
suitable technique to study them.