Acoustic wave propagation in liquid media containing many parallel air-filled cylinders is considered. A self-consistent method is used to compute rigorously the propagation, incorporating all orders of multiple scattering. It is shown that under proper conditions, multiple scattering leads to a peculiar phase transition in acoustic propagation. When the phase transition occurs, a collective behavior of the cylinders appears and the acoustic waves are confined in a region of space in the neighborhood of the transmission source. A novel phase diagram is used to describe such phase transition.When propagating through media containing many scatterers, waves will be scattered by each scatterer. The scattered wave will be again scattered by other scatterers. Such a process will be repeated to establish an infinite recursive pattern of multiple scattering, effectively causing the scattering characteristics of the scatterers to change. Multiple scattering of waves is responsible for many fascinating phenomena [1], including modulation of ambient sound at ocean surfaces [2], acoustic scintillation from turbulent flows [3], white paint, random lasers [4], electrical resistivity, and photonic band gaps in periodic structures [5]. More interesting, perhaps, under proper conditions multiple scattering leads to the unusual phenomenon of wave localization, a concept introduced by Anderson [6] to explain the conductor-insulator transition induced by disorders in electronic systems. That is, the electrical conductivity can be completely blocked and electrons remain localized in the neighborhood of the initial emission site due to multiple scattering of electronic waves by a sufficient amount of impurities in solids. By analogy, it has been conjectured that similar localization effect may also exist in the transmission of classical waves in randomly scattering media.Considerable efforts have been devoted to propagation of classical waves in random media. Localization effects have been reported for microwaves in 2D random systems [7], for acoustic waves in underwater structures [8], and for light [9]. Research also suggests that acoustic localization may be observed in bubbly liquids [10,11]. Despite the efforts, however, no deeper insight into localization can be found in the literature, as suggested by Rusek et al. [12]. The general cognition is that enhanced backscattering is a precursor to localization and waves are always localized in 2D random systems. Important questions such as how localization occurs and manifests remain unresolved. It is also unknown how many types of localization exist. It is believed that localization is a phase transition. However, how to characterize such a phase transition has not been considered in the literature. A deeper question may concern whether wave localization corresponds to a symmetry breaking and whether the collective behavior often seen in phase transitions such as superconductivity exits. This paper attempts to shed light on these questions.In this paper, we present a rigorous stud...