In this work, a new method to evaluate the reaction kinetics
of
different stimulation fluids with carbonate rocks was introduced.
NMR diffusion measurements were used to determine the acid diffusion
coefficient and the acid tortuous path inside carbonate rocks. Reaction
kinetics can also be evaluated using rotating disk apparatus (RDA)
in which a disc is rotated in the bulk fluid at different rotational
speeds. RDA does not represent the actual, restricted acid diffusion
that takes place in the porous media because only the surface of the
rock is exposed to the reaction and the acid is not confined in the
porous media. NMR diffusion measurements can accurately describe and
determine the acid restricted diffusion in porous media. The diffusion
coefficient of the acid is a crucial term in describing the reaction
kinetics of acids with carbonate rocks. It is also used to predict
the optimum injection rate required during the acidizing treatment
and the soaking time for different fluids required to remove scales
and deposits in the wellbore. The restricted diffusion was determined
for different fluids such as GLDA chelating agent, HEDTA chelating
agent, and EDTA chelating agent. Core flooding experiments for each
fluid were conducted to determine the optimum injection rate. NMR
restricted diffusion measurements then were conducted to determine
the restricted diffusion and in turn to determine the optimum injection
rate. The optimum injection rate estimated from the NMR was compared
to that from the core flooding experiments. The results were a good
match showing that NMR is a suitable, reliable, and robust method
to evaluate reaction kinetics of different fluids with carbonate rocks.