Lightweight, flexible, and noncombustible thermo-acoustic
insulating
(TAI) materials have great potential in vehicles, cold-chain transportation,
and aerospace engineering, where weight and space savings are critical.
However, the TAI capabilities of many commodities are hindered by
the lack of diverse and reasonable resonant cavities with broadband
and highly efficient acoustic responsiveness. This study demonstrates
a layer-by-layer freeze-casting method for superelastic cellular aerogel
construction from varied nanofibers and ice particulates with widely
distributed resonant cavities from 0.5 to 300 μm. The method
enabled the cumulative freezing of the nanofiber solution from one
side to the other side, resulting in vertical pore channels with random
holes across the entire freezing distance. The formed cellular networks
of stable hinged ternary nanofiber membranes, functionalized as ultrathin
nanofiber drums, exhibit strong resonances and efficiently dissipate
sound waves in a broad frequency range. A high noise reduction coefficient
of 0.65 at a frequency range of 63–6300 Hz and a low thermal
conductivity of 0.026 W m–1 K–1 at room temperature was obtained. This work presents the bottom-up
fabrication of high-performance TAI aerogels that are beneficial for
practical energy-saving devices and buildings and broadband acoustic
absorption applications.