A new acousto{electrical method making use of transient transverse acousto{electric voltage (TAV) to study solid state structures is reported. This voltage arises after a surface acoustic wave (SAW) generating the signal is switched o . Related measurements consist in detecting the shape of transient voltage and its spectral and temperature dependence. Both theory and experiment show that this method is an e ective tool to characterize trapping centers in the bulk as well as at surfaces or interfaces of epitaxial semiconductor structures.