CO 2 sequestrated in deep geological formations can be in gaseous, supercritical or liquid state, depending on subsurface pressure and temperature. In this work, CO 2 core flooding experiments are carried to investigate the effect of CO 2 phase on drainage process, especially parameters, such as capillary displacement pressure, relative permeability and displacement efficiency. The results indicate that CO 2 phase significantly affect their breakthrough. The breakthrough took place with the least volume of injected liquid CO 2 (LCO 2), and with the largest volume of gas CO 2 (gCO 2). The capillary displacement pressure can be measured based on the jumps in the pressure profiles, and it shows the largest jump in gCO 2 drainage. The relative permeability is the largest in LCO 2-water displacement and the smallest in gCO 2-water displacement. The displacement efficiency can be improved by increasing capillary number when it is smaller than a critical value around 2×10-8. Keywords: CO 2 phase; CO 2 breakthrough time; capillary displacement pressure; relative permeability; water recovery *Manuscript Click here to view linked References *Declaration of Interest Statement