2010
DOI: 10.1002/ejic.201000168
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Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling

Abstract: Actinyl oxysalts with TO4 tetrahedral oxyanions (T = S, Se, Cr, Mo) demonstrate a remarkable structural diversity, owing to the flexibility of the An–O–T linkages, which results in a multitude of topological and geometrical variations. Application of graph representation of structural units allows topological classification of structures and analysis of topological and geometrical isomers. In some organically templated structures, isomerism is controlled by the interplay of hydrophobic/hydrophilic interactions… Show more

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Cited by 64 publications
(46 citation statements)
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“…In the framework of this approach [36][37][38], the U and Se coordination polyhedra are symbolized by black and white nodes, respectively. The vertices are linked by an edge if two respective polyhedra share a common oxygen atom.…”
Section: Topological Analysismentioning
confidence: 99%
“…In the framework of this approach [36][37][38], the U and Se coordination polyhedra are symbolized by black and white nodes, respectively. The vertices are linked by an edge if two respective polyhedra share a common oxygen atom.…”
Section: Topological Analysismentioning
confidence: 99%
“…9 Actinide sulfates, chromates and selenates are known to form diverse and complex structures with such interesting structural features as cation-cation interactions, microporous frameworks and nanotubules. [10][11][12][13][14][15][16] Actinide molybdates and tungstates may adopt structure types more resembling dense complex oxides than oxosalts. 4 In comparison to molybdates, uranyl tungstates are less studied with relatively few reports available in the literature.…”
mentioning
confidence: 99%
“…The relations between the triplets are illustrated in Figure 6b, which represents an analogue of de Brujin diagram for cellular automata [25][26][27] that was considered as a model of crystallization processes [28,29]. The arrow lines in the diagram indicate the only possible sequence of triplets starting at the preceding triplet and ending at the following.…”
Section: I-iii Ii-iv I-v Ii-vii Iii-i Iv-ii V-viii Vi-i Vii-vi Viii-iimentioning
confidence: 99%