The effect of increased wastewater salinity on the physical characteristics of activated sludge flocs was studied. Samples of activated sludge were exposed to increments of NaCl and the physical structure of the individual flocs, was then investigated. A time response of the flocs to these changes was also measured. Two separate series of tests were run and for both series, it was determined that as the NaCl concentration increased, the mean floc area, equivalent diameter, perimeter and longest dimension all increased, with the flocs becoming more elongated with decreasing shape factor. The mechanism involved in the increase of the floc sizes is considered to be a combination of electrostatic and hydrophobic interactions. Examination of the size distributions revealed that the data were best fitted by a log normal distribution and that, as the NaCl concentration was increased, the distribution of the characteristic tended to shift towards a higher proportion of larger values, or smaller values for the shape factor results. Both the porosity and boundary fractal dimension were found to provide different values in the two series of tests. The flocs were found to exhibit two distinct Sierpinski fractal dimensions, thus indicating the presence of two pore size populations. The increasing salinity had little effect on the smaller pore size population, but a significant effect on the larger pore size population. The time response test indicated that the flocs achieved the new characteristics in about 15 minutes.