2024
DOI: 10.1002/ange.202416853
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Activation and Deactivation of Chirality Transfer in the Superbundles of Sequence‐defined Stereoisomers

Zhihong Yu,
Rui Tan,
Xiaoxiao Cheng
et al.

Abstract: Discrete oligomers can be used to precisely evaluate the structure‐property relationship and enable unique chiroptical activities, however, the role of stereochemical sequences in chirality transfer is still unclear. Herein, we report the successful synthesis of a series of sequence‐defined chiral azobenzene (Azo) oligomers via iterative stepwise chain growth strategy, and the discovery of controllable activation and deactivation of chirality transfer. Sequence‐defined stereoisomers with one single chiral (L o… Show more

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