Wet
air oxidation (WAO) of grape pomace, an organic waste generated
in massive amounts worldwide and with low biodegradability due to
phenol-acid content, was performed to evaluate the potential production
of an organomineral fertilizer with biostimulant properties. The synergistic
effect of co-processing kimberlite rock powder, a diamond mine tailing,
was tested as a potential waste-derived catalyst due to its ferrous
iron content and as a potential carbon sink due to its alkaline earth-silicate
content. The gaseous, liquid, and solid phases were characterized
by gas chromatography, wavelength-dispersive X-ray fluorescence, pH,
loss on ignition, thermogravimetric analysis, attenuated total reflectance
Fourier-transform infrared spectroscopy, calcimetry, and turbidity,
and the results were also subjected to bivariate and multivariate
analyses (Pearson correlation coefficient and principal component
analysis) to uncover data patterns. The products obtained from WAO
were evaluated in bioassays for their soil amendment properties: one
assay as a nutrient source to alfalfa (Medicago sativa L) and another assay with soybean (Glycine max L. Merrill) under abiotic stress. The results revealed that temperature
and kimberlite play an important role in the oxidation performance
of steadfast humic-like substances, and kimberlite is a sink for part
of the CO2 that is produced during WAO via mineral carbonation. The WAO products were found to possess beneficial
nutrients and properties as soil amendments in terms of sustaining
early plant development and alleviating salinity stress.