Activation of h‐BN and SiC monolayer sheets through foreign atom substitution; a comparative study based on ab‐initio method

Abstract

Here, we studied two different 2D monolayer systems (i.e., h-BN and SiC), which exhibit unique electronic and magnetic properties. We analyzed the effects of Transition Methods (TM) doped atoms (i.e., Mn, Ni, and Sc) on the single vacancy (SV) h-BN and SiC systems using first principles calculations. Through comparison we found that Mn substitution in SV h-BN and SiC can modify their electronic and magnetic properties having larger magnetic moment as compared to other dopants (i.e., Ni and Sc.). Band structure and PDOS plots confirmed that TM doping in SV h-BN can convert the pure h-BN (insulator) to semiconductor, metal, or semi-metal, it is also observed from the results that Mn-doped h-BN has higher band gap approximately equal to Eg $ 2.7 eV during the negative spin and has smaller band gap, that is, (Eg $ 1.1 eV) during the positive spin. Similarly doping with the TM atoms on the SV SiC monolayer system can convert pure SiC to metal or half metal. In addition, Mn-doped SiC showed semimetal property having 0 eV band gap. These finding will help us to vary the electronic and magnetic properties of the pure h-BN and SiC sheets which can be used for the optoelectronic and spintronic applications.

Highly sensitive work function type room temperature gas sensor based on Ti doped hBN monolayer for sensing CO2, CO, H2S, HF and NO. A DFT study

“…[19][20][21] The reason behind is the weak interactions of hBN monolayer with gas molecules due to inherent chemical inertness of hBN. Therefore researchers have countered this problem and enhanced the gas sensing by surface activation through, 22,23 foreign element doping [24][25][26] and defect engineering. 27,28 It has been proved that metal decoration on 2D materials can significantly enhance the gas adsorption affinity of 2D materials.…”