In this work, silver-free
UV-curable powder coatings with antimicrobial
properties were developed. The coatings were made using acrylic resin
containing epoxy groups and environmentally friendly biocides such
as chitosan or chitosan intercalated in montmorillonite. The UV-curing
reaction involved the cationic polymerization of epoxy groups initiated
by triarylsulfonium hexafluorophosphate as the photoinitiator. The
resulting coatings were evaluated through a series of tests including
roughness, gloss, scratch resistance, hardness, adhesion to steel,
water contact angle, and antimicrobial resistance. The mechanism of
antimicrobial activity was also proposed.