2008
DOI: 10.1002/ange.200704614
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Activation of sp3 Carbon–Hydrogen Bonds by a Ruthenium(II) Complex and Subsequent Metal‐Mediated CC and CN Bond Formation

Abstract: Lieber H als N: Das Komplexfragment {TpRuII(PMe3)Me} aktiviert die C(sp3)‐H‐Bindungen funktionalisierter Substrate eher als Heteroatomfunktionalitäten. Die C‐H‐Aktivierung von Acetonitril, Aceton und Nitromethan führt zur Freisetzung von CH4 und anschließenden C‐C‐ oder C‐N‐Kupplungen. Beispielsweise entsteht aus Aceton und Acetonitril ein freies Enamin (siehe Schema).

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Cited by 6 publications
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“…Aryl–heterocycle C–N cross‐coupling chemistry is currently an important area of research, generating biologically important compounds 5,7. Coupling reactions with metal centers, such as copper,8 palladium,9a rhodium,10a ruthenium,10b and cobalt/manganese,10c or a base9b have been reported in the literature. In the vast number of cases, aryl chlorides, bromides, iodides, and sulfonates were used as precursors in the reactions with amines and other homologues.…”
Section: Introductionmentioning
confidence: 99%
“…Aryl–heterocycle C–N cross‐coupling chemistry is currently an important area of research, generating biologically important compounds 5,7. Coupling reactions with metal centers, such as copper,8 palladium,9a rhodium,10a ruthenium,10b and cobalt/manganese,10c or a base9b have been reported in the literature. In the vast number of cases, aryl chlorides, bromides, iodides, and sulfonates were used as precursors in the reactions with amines and other homologues.…”
Section: Introductionmentioning
confidence: 99%