Additive manufacturing (AM) can be advanced by the diverse
characteristics
offered by thermoplastic and thermoset polymers and the further benefits
of copolymerization. However, the availability of suitable polymeric
materials for AM is limited and may not always be ideal for specific
applications. Additionally, the extensive number of potential monomers
and their combinations make experimental determination of resin compositions
extremely time-consuming and costly. To overcome these challenges,
we develop an active learning (AL) approach to effectively choose
compositions in a ternary monomer space ranging from rigid to elastomeric.
Our AL algorithm dynamically suggests monomer composition ratios for
the subsequent round of testing, allowing us to efficiently build
a robust machine learning (ML) model capable of predicting polymer
properties, including Young’s modulus, peak stress, ultimate
strain, and Shore A hardness based on composition while minimizing
the number of experiments. As a demonstration of the effectiveness
of our approach, we use the ML model to drive material selection for
a specific property, namely, Young’s modulus. The results indicate
that the ML model can be used to select material compositions within
at least 10% of a targeted value of Young’s modulus. We then
use the materials designed by the ML model to 3D print a multimaterial
“hand” with soft “skin” and rigid “bones”.
This work presents a promising tool for enabling informed AM material
selection tailored to user specifications and accelerating material
discovery using a limited monomer space.