Activity Measurement of Gallium in Ga–Bi and Ga–Sb–Bi Alloys by EMF Method Using Zirconia as Solid Electrolyte

Experimental investigation and thermodynamic calculation of Bi–Ga–Sb phase diagram

“…Z ˇivkovic ´et al [10][11][12] presented new calculation results on thermodynamic properties of the Bi-Ga-Sb system. Also, based on the obtained cooling curves and microstructure analysis of the investigated samples by optical microscopy, phase diagram of the Bi-Ga-Sb system was investigated Katayama et al 13 measured the electromotive force of galvanic cells with zirconia solid electrolytes to determine the activity of gallium in liquid Bi-Ga-Sb alloys in the temperature range of 1050-1150 K.…”

“…Katayama et al 13 measured the electromotive force of galvanic cells with zirconia solid electrolytes to determine the activity of gallium in liquid Bi–Ga–Sb alloys in the temperature range of 1050–1150 K.…”

Activities of Al in the Al+Ga+Bi+Sb system in the temperature range (1173 to 1323) K

“…The binary and ternary parameters involved in equation (6) are used from the available literature data [2,[6][7][8][9][10] and are listed in table 5. Table 6 …”

Thermodynamic Investigation of Liquid Alloys in Ga-Sb-Bi-Sn System

“…One among interesting multicomponent GaSb-based systems is a quarternary Ga-Sb-Bi-Sn system. There are a lot of literature data concerning with the thermodynamics of its constituent binary systems Ga-Sb [1][2][3][4][5][6][7], Ga-Bi [8][9][10][11][12], Ga-Sn [13][14][15][16], Bi-Sb [17][18][19], Sb-Sn [20] and Bi-Sn [21], as well as for the ternaries Ga-Sb-Bi [8,[22][23][24], Ga-Sb-Sn [25,26], Ga-Bi-Sn [27] and Sb-Bi-Sn [28], while no references on thermodynamic behavior of quarternary Ga-Sb-Bi-Sn alloys are available up to now.…”